The vapor pressures of benzene, toluene and a xylene are 75 Torr, 22 Torr and 10 Torr at 20°C. Which of the following is not a possible value of the vapor pressure of an equimolar binary/ternary solution of these at 20°C? Assume all form ideal solution with each other.
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The vapor pressures of benzene, toluene and a xylene are 75 Torr, 22 Torr and 10 Torr at 20°C. Which of the following is not a possible value of the vapor pressure of an equimolar binary/ternary solution of these at 20°C? Assume all form ideal solution with each other.

(A) 48½

(B) 16

(C) 35⅔

(D) 53½

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Correct option is (D).

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